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Textile Engineering & Fashion Technology

Research Article Volume 7 Issue 3

A critical study of the effects of flame retardancy on different knit fabrics

Sheikh Sha Alam

Department of Textile Engineering, Port City International University, Bangladesh

Correspondence: Sheikh Sha Alam, Assistant Professor and Chairman, Department of Textile Engineering, Port City International University, Chattogram, Bangladesh

Received: May 16, 2021 | Published: May 26, 2021

Citation: Alam SS. A critical study of the effects of flame retardancy on different knit fabrics. J Textile Eng Fashion Technol. 2021;7(3):105-109. DOI: 10.15406/jteft.2021.07.00275

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Abstract

A novel flame retardant especially Pekoflam HFC was synthesized to improve the flame retardancy of fabric. Pekoflam HFC is especially suitable for flame retardant back coatings of synthetic fibre based home textiles and high-performance technical textiles. The flame retardancy of the samples was characterized by the spray method and the vertical burning test. The results indicated that the flame retardant had excellent flame retardancy and durability for cellulosic fabrics. The cotton knit fabric treated with Pekoflam HFC obtained the optimum flame retardancy with the decreased char length. Combustion behaviors of treated cotton fabric were tested by manual observation. After treatment, it found that the ignition time increased, and the values of total heat release, heat release rate and mass loss decreased. The strength and durability of treated fabric were studied by tear force test and washing durability test, respectively.

Keywords: pekoflam HFC, flame retardant, spray techniques, cotton fabrics, flammability, durability

Introduction

Textile substrates, particularly natural textiles, are easily ignited and highly flammable, posing a serious threat to persons and their belongings.1 Cotton is widely utilized in the domestic and industrial fields due to its favorable features such as regeneration, biodegradation, softness, comfort, warmth, and hygroscopic qualities. It is one of the most significant ecological textiles. On the other hand, this fabric has a strong inflammability due to its low limiting oxygen index and combustion temperature, which severely limits its use.2–6

Flame retardants are a class of chemicals that are added to combustible materials to prevent fires from starting or to slow the progress of a fire so that more time is available to escape.7

The flame retardant effect can be fast to mild washing conditions in combination with suitable hydrophobic binders. Due to the high surface area and the very low water solubility, the addition of a dispersing agent can be necessary when preparing the coating paste. As a combination with certain polymer binders can result in some cases in a destabilization of the polymer dispersion, proper selection of the binder system and adaptation of the dispersant system can be required.8

Hundreds of different flame retardants are available. Chemical structure and characteristics are frequently used to categorize them. Flame retardants are classified according to their content of bromine, chlorine, phosphorus, nitrogen, metals, or boron.9

Pekoflam HFC is especially suitable for flame retardant back coatings of synthetic fibre based home textiles and high-performance technical textiles. As a powder without substantial affinity to the textile material, it requires a combination with compatible polymer dispersions.10–12 The flame retardant effect can be fast to mild washing conditions in combination with suitable hydrophobic binders.13,14 In this case, Pekoflam HFC performs well with synthetic fabrics and mixes. It has better binder compatibility and a lower impact on rheological behavior commonly observed by increased viscosity when compared to other phosphorus-based powder flame retardants.

The Oeko-Tex Standard 100 recognized Pekoflam HFC as the first flame-retardant powder for the textile sector. The capacity of Pekoflam HFC to combine the effects and qualities of specified halogenated and non-halogenated technologies in a fire protection solution for diverse coating polymers15 is its key benefit. Pekoflam HFC thus provides a long-term sustainable option for synthetic textile applications, meeting the Oeko-Tex Standard 100 standards and reacting to the general trend toward more ecologically friendly materials and end-products with lower health hazards.16

Pekoflam HFC is suitable for use in selected solvent-based coating systems but also for water-based coatings if combined with appropriate dispersing/wetting agents. Due to its very high-temperature stability and very low yellowing, as well as its low hygroscopic nature it is especially suitable for use in interior and transportation textiles, as well as for industrial protective wear.17,18

It can be combined with suitable polymer dispersions, preferably acrylates and polyurethanes. Depending on the application system and solvent type combination is also possible with PVC plastisols or solvent-based polyurethanes. In principle, it recommends preliminary lab trials to check the stability for combinations with other products.19–21

Due to the high surface area and the very low water solubility, the addition of a dispersing agent can be necessary when preparing the coating paste. Adaptation of the dispersant system can be required to adjust the system to the desired process parameters. Care should be taken to ensure that the necessary curing temperature for the binder used is employed, in case that coating fast to washing is required.22

This project work aims to improve the flame retardancy property of fabric and to minimize the health risk from any kinds of fire or flame by using Pekoflam HFC flame retardant finish. After using chemical finish on 3 types of fabric, the flame retardancy has been tested and char length has been determined.

Materials and methods

Materials

Fabrics: 100% Cotton knit Fabric has been used throughout the experiment and which is received from Base Textiles Ltd. Fabric. In this experiment, 3 different fabric samples were used such as a single jersey, 1×1 Rib, and Terry.

Chemicals and reagents

Pekoflam HFC is a phosphorus/nitrogen organic chemical that performs well on synthetic textiles, such as polyamide fibres and blends. When compared to frequently utilized nitrogen, the unique chemistry is more efficient. It can be used in both water-based and Oeko-Tex standard 100 compliant green solvent-based coating processes. Because of the ecological profile, it can be used for both indirect and direct skin contact. The capacity of Pekoflam HFC to combine the effect and qualities of selected halogenated and non-halogenated technologies in a fire protection solution for various coating polymers is its key benefit. Pekoflam HFC thus offers a sustainable long term alternative for synthetic textiles application, meeting the Oeko-Tex standard 100 and responding to the general trend towards more environmentally compatible materials and products that pose a significantly lower health risk (Figure 1) (Table 1).

Figure 1 Pekoflam HFC.

Appearance

White powder

Chemical character

Organic phosphorus/nitrogen compound

Ionic character

None

Solid content

About100%

Density

About 1.4 g/cm3

pH

About 4- 6

Phosphorus content

About 20-21 %

Water content

0.25%

Solubility

Insoluble in water (<1 g/L) and common organic solvents.

Table 1 Properties of the Chemical

Method of experiment

Conventional scouring-bleaching: The sample fabrics (grey knit fabrics) were collected from Base Textiles Ltd., Bangladesh. Then the fabric was treated as single bath conventional scouring-bleaching. Sample dyeing machine of Base Textiles lab was used for the exhaust process. For this treatment 1.5g/l wetting agent, 1.5g/l sequestering agents, 4g/l caustic soda, 1.5g/l detergents, 1.5g/l stabilizers, 6g/l hydrogen peroxide, M:L ratio was 1:20, and temperature 110˚C for 45 minutes.

Sample preparation: After scouring and bleaching, the samples were prepared for the next process. The samples were cut at 8 cm widthwise and 30 cm lengthwise to perform the experimental work successfully.

Chemical treatment: In this experiment, the samples were developed at a one-step finishing process and that was the spray method or spray technique. Pekoflam HFC is first filled in a spray bottle and then a different structure of the cotton knit fabric is placed on the table serially one by one. After that, Pekoflam HFC flame retardant was sprayed in the fabric cutting specimen gradually. After completing the spray process, chemically treated specimens were dried in curing knit for 20 minutes. Then the vertical burning test was done to determine the thermal stability of the different knit structured fabric (Figure 2).

Figure 2 Pekoflam HFC spraying on fabric samples.

Method of testing vertical burning test: After drying, those specimens were undertaken for the vertical burning test. In this test process, firstly, the specimen was hanged through a burette stand. A gas burner was placed just below the fabric end. By considering a constant flame length which was 5 cm and a constant time for burning which was also 5sec. Then started burning the sample which measurement was 30×8cm. At first, the raw sample was burned which remained untreated. After that, the treated samples were burned. After burning the char length for both treated and untreated specimen were measured. And finally, noted the data for further analysis.

Results and discussion

Flame retardant test

In this experiment, the vertical flam test method (ASTM-6413) was used to determine the flammability test and analyses how LOI (Limiting Oxygen Index) effect flammability. LOI is defined as the minimum amount of oxygen in the oxygen/nitrogen mixture required to support combustion. Fibres having LOI value 21 or below ignite easily and burn rapidly in the open atmosphere. Sample with LOI above 21 ignites but slowly (Figure 3).

Figure 3 Flame retardant test (a. Vertical burning test; b. Burned sample for single jersey; c. Burned sample for 1*1 Rib; and d. Burned sample for terry fabric).

Flame retardant test on single jersey structure

Pekoflam HFC treated fabric shows flame retardant properties on different structured woven fabric (as shown in (Table 2). During this experiment burning time and char length is calculated. Ignition time is the total time of burning time of a specimen. Char length is the total damage length of the fabric (Figure 4).

Observation

Flame height (cm)

Ignition time (sec)

Char length (cm)

Untreated

Treated

Sample 1

5

5

7

3.4

Sample 2

5

5

6

3.1

Sample 3

5

5

6

4.1

Mean

 

 

 

3.53

Table 2 Flame retardant test of single jersey fabric

Figure 4 Pekoflam HFC effect of after treated (on the left) and untreated (on the right) samples on single jersey fabric.

Flame retardant test of 1x1 rib structure

Table 3 shows the data of char length. It shows that treated fabric is burned more than 1x1 rib untreated fabric. It exclaimed that after applying Pekoflam HFC fire retardance property increase then untreated fabric (Figure 5).

Observation

Flame height (cm)

Duration (sec)

Char length (cm)

Untreated

Treated

Sample 1

5

5

5

2.8

Sample 2

5

5

4.5

2.3

Sample 3

5

5

5.2

1.9

Mean

 

 

 

2.33

Table 3 Flame retardant test of 1x1 rib

Figure 5 Pekoflam HFC effect of after treated (on the left) and untreated (on the right) samples on 1x1 rib fabric.

Flame retardant test of terry structure

Finally, In Table 4 presented all data with char length with treated and untreated fabric. It shows that Pekoflam HFC increases LOI in the fabric surface. The untreated bleached fabric has a certain amount of LOI. So it burns rapidly. But treated fabric contains more LOI so it can resist rapid burn (Figure 6).

Observation

Flame height (cm)

Duration (sec)

Char length (cm)

Untreated

Treated

Sample 1

 

5

3

0.9

Sample 2

5

5

3.2

1.3

Sample 3

5

5

3

0.7

Mean

 

 

 

0.97

Table 4 Flame retardant test of terry fabric

Figure 6 Pekoflam HFC effect of after treated (on the left) and untreated (on the right) samples on terry fabric.

From this figure, it shows that the treated status of Single Jersey, 1x1 Rib, and Terry Fabric (Figure 7). From this data, it concludes that single jersey caught fire rapidly than 1x1 rib and terry even on treated status. Because of its structure and nature, it catches fire rapidly and shows lower LOI. Single jersey shows very poor fire retardant than 1x1 rib and terry fabric. Pekoflam HFC has a nitrogen compound that can make a coating on fabric surface that can reduce LOI of fabric.

Figure 7 Char length vs fabric structure bar chart.

Conclusion

Pekoflam HFC is a halogen-free organic phosphorus or Nitrogen compound. Nitrogen compound can make a coating on the fabric surface and increase LOI value. Different structure of fabric shows different flame retardancy property after finishing the same flame retardant chemical. Fire retardant chemical can spray on fabric to improve its retardancy. The presence of Phosphorus/Nitrogen compound deposited on treated fabric can most positive parameter of char forming and decreases the flammability of fabric. More LOI value means more Flame retardant fabric. It is more environmentally-compatible materials and end-products that pose significantly lower risks to health. Finally, it found that Pekoflam HFC reduces fire hazard. In this project, it shows that with the increment of chemical‘s use on fabric in our daily life it will be beneficial to use this product as a flame retardant. To ensure the properties of flame retardant fabric, it has a great advantage to reduce fire accidents, this product can provide extra safety to our industry workers working inside the flame. Because it‘s quite easy to provide flame retardant fabric than to provide an extra safety suits and it is far comfortable then the suits.

Acknowledgments

The author would like to acknowledge M. Ahmed, Professor, Department of Textile Engineering, Port City International University, Chattogram, Bangladesh to provide proper guidelines to complete this project work successfully.

Funding

None.

Conflicts of interest

The authors report no declarations of interest.

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