Review Article Volume 6 Issue 4
Air Pollution Research Department, Environmental Research Division, National Research Center, Egypt
Correspondence: Atef MF Mohammed, Air Pollution Research Department, Environmental Research Division, National Research Center, Giza, Egypt
Received: September 30, 2020 | Published: October 23, 2020
Citation: Mohammed AMF, Saleh IA, Saleh NM. Review article: air quality and characteristics of sources. Int J Biosen Bioelectron. 2020;6(5):85-91. DOI: 10.15406/ijbsbe.2020.06.00193
Atmospheric pollution is a major problem facing all nations of the world. Air quality management leads to prevent or decrease harm impacts, by applying environmental policies, legislation, and manage ambient air quality monitoring. Air quality assessments help air quality management to understanding of how pollutant sources, characteristics, topography, and meteorological conditions contribute to local air quality. This review article is concerned with the reports concerning air quality around the world, which published by different national and international environmental affair organizations. The air quality monitoring data collected in Egypt by national network stations (EEAA) and (EMC) and published in reports of Central Agency for Public Mobilization and Statistics (CAPMAS).
Keywords: ambient air quality (AAQ), indoor air quality (IAQ), national ambient air quality standards (NAAQS), Egypt
Air pollution (Poor air quality) is considered one of the major challenges facing Egypt.
Air quality is referring to the concentration of harmful substances (pollutants) present in the atmosphere. It is determined by monitoring a variety of pollution indicators. Good air quality is necessary for preserving the balance of life on earth for humans, plants, animals and natural resources. Poor air quality can affect human health and/or the environment.1
Ambient air quality (AAQ)
Ambient air quality monitoring: Monitoring air quality indicators in ambient air provides data regarding the status of present air quality. It helps decision makers to put and evaluate environmental policies. Establishment of air quality monitoring network is based on the air quality indicators.2 The usual air quality indicators monitored include dust deposition, particulate matter (PM10 and PM5), nitrogen dioxide (NO2), sulfur dioxide (SO2), carbon monoxide (CO), ground level ozone (O3) and lead (Pb). Ambient monitoring is often necessary as a condition of Industrial Emissions Licensing, permit, planning condition,1
Air quality management: Air quality management leads to prevent or decrease harm impacts, by applying environmental policies, legislation, and manage ambient air quality monitoring. Air quality assessments help air quality management to understanding of how pollutant sources, characteristics, topography, and meteorological conditions contribute to local air quality. The air quality assessment tools are: (1) land use, (2) mobile monitoring, (3) emission inventories, (4) dispersion modeling, and (5) source apportionment.3
National Ambient air quality standards (NAAQS)
The nature and concentration of air pollution varies from city to city. Where, the first requirement to air quality management is the creation of local air quality monitoring network to collect data used to develop an air quality policy.4 Second step is National Ambient Air Quality Standard (limitation or guidelines). NAAQS are standard concentrations of criteria pollutants in the air, and typically refer to ambient air. The NAAQS is established by the national environmental agency. The regulations for different countries around the world are listed in Table 1.5–10 Primary standards are designed to protect human health. Secondary standards are designed to protect crops, vegetation, soils, Statues, animals, wildlife, weather, and climate. As well as, to prevent damage of property and transportation hazards. The National Ambient Air Quality Standards (NAAQS) have been set for six principal pollutants known as air quality indicators (criteria pollutants). These are particulate matter, sulfur oxides, nitrogen dioxide, carbon monoxide, lead, and ground-level ozone.11
Indoor air quality (IAQ)
It refers to the air quality within and around buildings and structures. Poor IAQ is affect on health, comfort, and well-being of residents of the building. Poor indoor air quality cause sick of building syndrome, impaired learning in schools, and reduced productivity. IAQ indicators are PM10, PM2.5, CO, radon, and volatile organic compounds (VOCs). The most effective ways to improve IAQ are to limit the sources of pollutants and to ventilate with clean ambient air.12
Characteristics of sources
Many pollutants contribute degradation of air quality; the pollutants of greatest concern include the “criteria pollutants”. These pollutants are particulate matter (PM), nitrogen dioxide (NO2), sulfur dioxide (SO2), carbon monoxide (CO), ground level ozone (O3) and lead (Pb).4,13 There are many sources of atmospheric pollution.4 The sources of air pollution are classified into:-
Ambient air pollutants: Air pollutants are gases or particles in the atmosphere which have been linked to harmful human health or environmental effects. Pollutants can be categorized according to these: formation, sources, and chemical composition and characteristics:4,13,14
Formation
Primary pollutants (directly emitted to the atmosphere), such as PM, SOx, NOx, CO, volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAH) and methane (CH4).4
Secondary pollutants (formed in the atmosphere from reaction between primary pollutants), such as ground O3 and secondary PM.14
Sources of air pollutants are classified into:
Natural sources include desert dust, sea spray, Volcanoes, and wildfires.4,13
Chemical composition and characteristics
Ambient air quality indicators are six PM, SO2, NO2, CO, O3 and Pb. Table 2 shows characteristics of sources of air pollutants and its contribution.4,11,13,14
Indoor air pollutants (IAP)
In developing countries, a major source of IAQ is the burning of biomass (e.g. wood, charcoal, dung, or crop residue) which used for heating and cooking. In many poor African countries, biomass is the main fuel for rural homes. Biomass and coal smoke emit many pollutants, including PM2.5, PM10, SOx, NOx, CO, VOCs, formaldehyde (HCHO), and benzene. Sources of indoor air pollution include:12,13,15
Site environment types
Descriptions of the environment type classifications used for classifying air quality monitoring sites are shown below:16
Case studies of ambient air quality (AAQ)
In Egypt; air pollution was studied in urban, suburban and rural districts of Greater Cairo area. Atmosphere in the urban area is more humid throughout the year if compared to the suburban area and during the months from October to January in addition to May if compared to the rural area. Urban atmosphere is always warmer than its surroundings throughout the year, except in November when there is a cool island.17 The major sources of air pollution are residential activities, vehicles and industrial centers (factories of Textile, steel, cement, chemical, fertilizer, petroleum, construction, brick and car industries and power plants),18 Kanakidou et al.19 showed that rural and suburban parts of the city have higher ventilation due to higher wind speeds than urban parts, which may lead to higher pollutant levels in the urban regions of Greater Cairo area. Hot desert cyclones associated with strong hot and dry winds often carrying dust and sand that increase particulate matter (PM) levels. Dust and sand storms frequently occur in spring and autumn. During winter the climate is generally cold, humid and rainy; while during the summer season the predominant weather is hot and dry. Residential combustion, on-road traffic and industrial activities are the major sources of air pollution in urban area of SO2 (71%), CO (35%) and NOx (50%) whereas VOC (37%) emissions are mostly from solvents use seconded by road transport. Anthropogenic PM5 in Greater Cairo area originates mainly (54%) from residential combustion and open burnings.19 The maximum concentrations of PM2.5, PM10 and Pb in Greater Cairo environments were (120, 200 and 1.1µg/m3, respectively) in background, (110, 210 and 1.5µg/m3, respectively) in residential, (130, 230 and 1.1µg/m3, respectively) in urban, (130, 250 and 11µg/m3, respectively) in industrial.19 The maximum concentrations of SO2, NO2, ground level O3 and CO in urban areas of Greater Cairo were 125µg/m3, 200ppbv and 91ppbv, 10 mg/m3 respectively.19
In Kenya; air quality was studied at two sites (urban site and suburban site) in Nairobi. PM5 concentration was 21μg/m3 at urban site and 13μg/m3 at the suburban site. Highest PM2.5 concentration was recorded during the cold and dry season (25μg/m3) and lowest during the short rains season (8.9μg/m3). PM2.5 sources in Nairobi include traffic, mineral dust, industry, combustion, biomass burning and sea salt (, 2014).
In Burkina Faso; carbon monoxide (CO) were examined in urban, roadside and in-traffic environment of Ouagadougou. Carbon monoxide was generated by incomplete combustion of fuels. CO concentrations in-traffic values (16 ppm) were 2–3 times higher than roadside values (6.5 ppm) and 10–12 times higher than urban values (1.5ppm).20
In Italy; the Concentrations of PCBs and PAHs were (20 - 200pg/m3 and 5 - 48ng/m3, respectively) in urban and (21-72pg/m3 and 0.52 - 15 ng/m3, respectively) in sub–urban sites. Urban areas are characterized by intense emissions from vehicles, incomplete combustion, and industrial activities. Higher air concentrations of PCBs were detected during the warmer periods (summer and spring), and higher concentrations for PAHs during the colder periods (autumn and winter), and attributed to different types of sources for PCBs vs PAHs.21
In Poland; aerosol particles were collected in different environments in Legnica (urban site) and Krako´w (rural site).22 Analysis of airborne particles from urban and rural environments revealed differences in partial concentration of 20 selected elements. Konarski et al.22 found more; Pb, Cr-20 times, As, Sr-10 times, Co-7 times, V, Y-3 times, Ti, Mn, Cu, Se-2 times and Fe, Ni, Zn, Br, Zr, Mo-2 times in urban than in the rural environment. In urban area contamination is due to road traffic, combustion and industrial emission, while in rural area contamination is due to pollen, animal and microbial allergens.
In Malaysia; PM10 concentration were monitored in urban, sub-urban and industrial areas. Result indicated that the highest concentration of PM10 was detected in urban areas, followed by industrial and sub-urban areas. The highest concentration of PM10 was recorded in the urban areas (116μg/m3) followed by industrial (101μg/m3), while the lowest concentration was recorded at sub-urban areas (94μg/m3). High concentrations of PM10 in urban areas might be due to many anthropogenic activities include vehicles emission, power plants, incinerators, cement and quarry industries, road dust, and open burning. In addition, In addition, haze phenomena from neighboring countries were also contributed to high amount of air pollutants in Malaysia.23
In India; ambient air concentration of PM10 and concentration of heavy metals was assessed at sub-urban and rural areas. PM10 concentrations are (37–959μg/m3) at the rural sites and (151–422μg/m3) at sub-urban sites. Conversely, lowest PM10 concentration recorded during February as result of removal of particles by heavy rain. Highest concentrations of heavy metals; Cr, Fe, Mn, Zn, and Al were 2.04, 30, 0.80, 7.13, and 15.6 ng/m3, respectively, at rural sites compared with 0.28, 0.37, and 0.02 ng/m3 for Ni, Cu, and Cd, respectively, at sub-urban site. Main sources of PM10 and heavy metals at sub-urban sites were road dust, traffic exhaust, tire abrasion, industrial emissions, and oil lubricants use. Heavy metals and PM10 at the rural sites originate from coal and wood burning, sugar mill and brick furnace emissions, fertilizers use, agricultural activity, road construction, and resuspended dust (Tyagi et al., 2011).
In China; air pollutants in Jinan (urban and suburban areas) are monitored in Jinan during 2013 to 2014, while the suburban area was less polluted than the urban area. The mean daily average concentrations of SO2, NO2 and PM5 were (95.4, 60.0, and 108.0 μg/m3, respectively) in urban area, (49.9, 38.9, and 70.7μg/m3, respectively) in suburb area. It was found that all three of the pollutants in urban area were 0.5–2 times higher than that in suburb, indicating that urban population represents a group more exposed to ambient air pollution than suburban population.24
In Nepal; the maximum concentrations of NO2 (270 -310μg/m3), CO (450 – 520μg/m3), and PM5 (226μg/m3) and PM10 (2,928μg/m3) was recorded during winter and spring seasons in Kathmandu Valley (urban areas). Common sources of air pollution are household combustion devices, forest fires, vehicles, haphazard digging of road, brick kilns, unplanned expansion of roads, and building materials waste on the busy road sides.25
Case Studies of indoor air quality (IAQ)
In Egypt; Culturable airborne fungal concentrations were assessed in different seasons. Samples were collected indoors of 43 homes in urban and rural environments. The median indoor total fungal concentrations were 608 CFU/m3 in the urban environment and 1,932 CFU/m3 in the rural environment, respectively. The greatest concentrations were found in the autumn and spring season. The concentrations and types of airborne fungi depend on time of day, climatic conditions, geographical location and type of vegetation. Airborne fungal concentrations in homes and schools ranged between 102 and 104 CFU/m3 in warm climates, and averaged 102 CFU/m3 in cold subarctic climates.26
In Poland; indoor air quality parameters (SO2, NO2, PM5 and PAHs) were characterized in naturally ventilated kindergartens in urban and rural area in Silesia, during spring season. Indoor pollutants in Poland emitted from house heating (coal and wood combustion) in domestic stoves, increased production in heating and power plants. The concentrations of SO2 (8.6μg/m3), NO2 (8.2μg/m3), PM2.5 (28.2μg/m3) and åPAHs (38.8ng/m3) in urban area, while concentrations of SO2 (10.1μg/m3), NO2 (8.2μg/m3), PM2.5 (31.9μg/m3) and åPAHs (45.3ng/m3) in rural area.27 Indoor daily concentrations of SO2 in Belgian primary schools during winter were (1.9 - 2.9μg/m3) in urban area and (1.4 - 3.5 μg/m3) in suburban area. 27 Lower concentrations of indoor SO2 were found in two Turkish schools 5.6 μg/m3 and 6.7 μg/m3. 27
In Malaysia; indoor air quality was studied in preschool children (urban area) and houses (suburban area), indoor pollutants included PM5, PM10, VOCs, aldehydes, mold, bacteria and Gram-negative bacteria. Indoor pollutants originated from indoor smoking, cooking activities, paint, wall, air cooling system and even outdoor air toward building residents. The concentration of indoor pollutants were PM2.5 (67 μg/m3), PM10 (74 μg/m3), VOCs (0.005 ppm), mold (402 CFU/m3), bacteria (550 CFU/m3) and Gram-negative bacteria (60 CFU/m3) in urban area. While concentration of indoor air pollutants were PM2.5 (119μg/m3), PM10 (131 μg/m3), VOCs (0.04 ppm), mold (275 CFU/m3), bacteria (142.5 CFU/m3) and Gram-negative bacteria (17.5 CFU/m3) in suburban area.28
Status of air quality
In different countries around the world, the regional and local environmental authorities carry out the monitoring of local air quality, to implement environmental management plans and environmental programs, and regulations to reach good air quality.
Air quality in Egypt
Air pollution is considered one of the major challenges facing Egyptian society. The Ministry of State for Environmental Affairs (EEAA) put air quality on the top of its priorities, and gives extraordinary attention to execute the strategies that face air pollution. Relatively with economic growth, industrial activities and other development processes. Air quality has been partially monitored in Egypt since 1970. Local air quality monitoring network has been updated continuously. It reaches a total of 92 stations covering different geographic locations in Egypt. Recent air quality states of the environment in Egypt published in reports of Central Agency for Public Mobilization and Statistics (CAPMAS), depending on air quality monitoring data collected by the national network stations of the ministry of environment (EEAA) and the ministry of health and population (EMC) compared with the ambient air quality standards for urban (Egyptian limits) are illustrated in Figure 1.9,29 In recent years, EEAA has developed the national network for monitoring ambient air pollutants to increase the efficiency of monitoring stations and supplying the stations with devices for weather factors monitoring.9 The national air monitoring network is considered as a basic reference for air quality indicators: I) SO2 which is emitted from power plants, various factories, and vehicles; II) NO2 which is produced from processes of the burning of fuels; III) CO which is emitted from incomplete combustion of fossil fuels, various industries, and vehicles; IV) Ground O3 which is higher during summer months than in winter as a result of the increase in sunshine hours; V) PM is emitted mainly from natural sources. The geographical nature, location of Egypt in the desert of North Africa, and the scarcity of rainfall lead to increase effect of natural sources on rates of suspended particulate matters. PM is considered the main indicator of air quality in Egypt; VI). Foundries are considered the most important source of industrial emissions of lead (pb). In Egypt, The contribution of mobile sources in air quality of Greater Cairo with PM is shown in Figure 2.9
Figure 1 Air quality in Egypt.29
Air quality in gulf countries
In United Arab Emirates (UAE); the main sources of air pollution are natural sources and industrial sources (such as fuel combustion, power generation, desalination, vehicles, ships, generators and oil and gas processing.10 In most areas, SO2, CO, NO2 and O3 concentrations are within the limits values in UAE. While the natural levels of suspended particles in the Emirate of Abu Dhabi are significantly higher due to the dry nature of the region, indicating the high natural levels due to the natural sources of these particles (Figure 3). In Kuwait; Sources of air pollution in Kuwait are vehicles, petroleum refineries, power plants, oil fields, construction, and industries.30 In Qatar; Air pollution sources in Qatar include vehicles, power plants, petroleum refineries, oil and gas processing, construction, and industries.31 In Kingdom Saudi Arabia (KSA); the sources include desert storms, oil refinery, power generation, plant a desalinization plant, industries, and vehicle fuels.32 Figure 4 show comparison of air quality in Kuwait, Qatar and Kingdom of Saudi Arabia.
Air quality in African countries
In South Africa sources of ambient air pollutants are natural sources (volcanoes, Wildfires domestic animals, and pine trees) and anthropogenic sources (vehicle emissions, fossil fuel burning, electricity generation, aircraft emissions, domestic fuel burning, biomass burning, and waste incineration). Indicator pollutants are PM, SOx, NOx, CO, VOCs, and CH4.33 In Rwanda; The main sources of anthropogenic air pollution are from industry, domestic fuel burning and road traffic.34 Key pollutants of concern in Rwanda are: NOx, NO2, SO2, PM10, PM2.5, O3, and CO.
Air quality in Asian countries
In recent years, poor air quality in different Asian cities was monitored. According to the WHO, air quality has worsened in Asian cities and presents a threat to human health.5,35,36 Figure 5 shows most polluted capital cities in Asia. In Singapore; air pollution sources include vehicular traffic, industrial activity, cargo ships, natural emissions and wildfires. In Bangladesh: The commercial sources include the combustion of fuels for power generation in industrial processes, powering motor vehicle, different construction, brick kilns, paper and pulp industries, oil refineries and burning of agricultural residues. In Bhutan; air pollutants are emitted during the combustion of biomass fuels and responsible for both indoor and outdoor air pollution.37 In India; the combustion of fuels in the domestic, industrial, transport sector, petroleum refineries, textiles, paper and industrial chemicals, vehicles and transport fertilizer manufacturing are the major sources of air pollutants. In Maldives; the main sources include the land and sea transport, power generation, construction activities, vehicles and domestic combustions. In Nepal; the major sources are vehicles, industrial (cement, brick, tile and textile factories) and incomplete combustion of fossil fuels. In Pakistan; the main sources are vehicles, refuse burning, open dumps burning, vehicular automobiles and aircrafts. In Sri Lanka; the emissions are from industrial activities, especially thermal power plants. In China; sources of pollution are including industrial facilities, biomass burning, automobiles, electric power plants, and fossil fuels.
Figure 5 Most polluted capital cities in Asia.16
Air quality in european countries
In UK; the main pollutants are NOx, SOx, VOC, NH3, CO, PM2.5, PM10, and heavy metals (HMs). Sources of pollutants are nature sources, agriculture, extraction and distribution of fuels, combustion plants, solvent use, electricity generation, and transport.16,38 In Scotland; the main sources of air pollutants are transport (diesel combustion), power stations and domestic combustion, agriculture (fertilizers and manure), road dust, brake, sea salt, construction, fuel combustion household products (aerosols, paints and disinfectants), domestic and industrial combustion, incomplete combustion of fossil fuels, solvents.39 In New Zealand; the major source of air pollution is combustion, whether it is from the burning of coal and wood to generate heat, or the burning of petrol and diesel in vehicles (SPIC, 2016).39 Combustion creates particles (PM10 and PM2.5) and gases (NOx, SOx, and, CO) that affect human health. Figure 6 & Figure 7 show air quality in Europe.
Figure 6 Air Quality in Europe during 2015.14
Figure 7 Air Quality in Europe during 2013-2016.14
Air quality in USA and Canada
In United States of America (USA); diesel engines, ports, vehicles, transportation sector, fuel combustion, incomplete combustion of fossil fuels and industrial processes are main sources of air pollution.40 In Canada; sources including mining process, Agriculture activities, construction, dust from paved and unpaved roads, industrial activity, smelting, home firewood burning, transportation, oil and gas industry and fuel for electricity and heating.14 Figure 8 show air quality in USA during 1990-2015 and Canada during 2002-2016.
Indoor air quality in developing countries
Poor air quality in developing countries is due to urbanization and industrialization.41 Figure 9 show indoor air quality of particulate matter (PM10 and PM2.5) in different developing countries during.
The relation between air quality and climate change
Air quality has been affected by changes in climate through different mechanisms. Direct effect is ability of black carbon to absorb heat from surroundings, and indirect effect is formation of soot clouds that acts as mirrors and reflects back heat towards earth’s surface. Also, increase ambient temperatures due to climate change, leads to increase formation of ground ozone (O3) from nitrogen oxides. On the other hand, sulfates and nitrates particles have a cooling effect, due to it reflects sunlight.42 Weather can affect air quality. Where, low temperatures during dry season make ambient air denser, move pollutants to lower altitude (breathing level). High pressure induces inversion layers, where cold air is trapped close to earth surface. This leads to prevents dispersion of pollutants, and lead to formation of smog. 42
In this paper air quality and characteristics of sources are reviewed around the world and concluded into:
The air quality monitoring data collected by national network stations (EEAA) and (EMC) should be reviewed by scientific committee to avoid conflict and errors before publishing it in reports of Central Agency for Public Mobilization and Statistics (CAPMAS). Improve data availability in all sectors which impact on ambient air quality with the aim of establishing mass emissions of key pollutants by sector. Also, the data collected should be used in emissions inventory. Encourage awareness activities (communicating with the public during poor air quality episodes), data dissemination, regulatory measures, vehicle inspection and maintenance; transportation planning and industry standards. Encourage use clean energy resources such as renewable energy from sustainable sources like solar and wind.
None.
The authors declare that there are no conflicts of interest.
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